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العنوان
Synthesis of highly unsaturated Azo organic compounds with expected biological activity /
المؤلف
Salem, Fatma Mostafa Mahmoud Mahmoud.
هيئة الاعداد
باحث / فاطمة مصطفي محمود محمود سالم
مشرف / احمد علي فضة
مشرف / علي عبد الهادي نصار
مشرف / محمد طه عبد العال
الموضوع
Bioorganic chemistry.
تاريخ النشر
2019.
عدد الصفحات
124 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Organic Chemistry
تاريخ الإجازة
2/4/2019
مكان الإجازة
جامعة المنوفية - كلية العلوم - الكيمياء
الفهرس
Only 14 pages are availabe for public view

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Abstract

Azo compounds have for great many years occupied dominant
position in the field of colouring matters due to their versitility. Azo dyes
containing at least one (N=N) sturcture in a molecule, are the most
important group of disperse dyes , and globaly comprise over 50 percent of
disperse dyes because of its strong tinctorial strength compared to
anthraquinone dyes, ease to make and a low cost of manufacture. Azo dyes
have a vivid colour in the yellow to blue green region because of varying
azo components with electronwithdrawing groups and coupling
components with electronwithdrawing groups. Among these, azo dyes
using heterocyclic amines have become important as they give brighter and
stronger results than these based on aniline -based diazo compounds .
Disperse dyes are organic colours with less water solubility, so they are
applied in colloidal aqueous dispersions to hydrophobic textile fibres in
which the dyes dissolve and produce the desired coloration
In continuation of our interest in the synthesis of pyrazolopyridine ,
this work reports the synthesis of some arylazo naphthol and coupling
products of active methylene compounds using a conventional method.
First, amild oxidation of pyrazolopyridine by Selenium dioxide give
compound 13. Then the compound 13 was reacted with malononitrile in
ethanol to give compound 14.